Progress and challenges of zinc‑iodine flow batteries: From
Zinc‑iodine redox flow batteries are considered to be one of the most promising next-generation large-scale energy storage systems because of their considerable energy density,
Zinc‑iodine redox flow batteries are considered to be one of the most promising next-generation large-scale energy storage systems because of their considerable energy density,
This work offers insights into controlling water transport behaviors for realizing long-life flow batteries.
This electrolyte engineering strategy, which stabilizes the anode within an advanced cathode chemistry, paves the way for highly durable and practical high-energy flow
The battery demonstrated stable operation at 200 mA cm−2 over 250 cycles, highlighting its potential for energy storage applications.
This electrolyte engineering strategy, which stabilizes the anode within an advanced cathode chemistry, paves the way for highly durable and practical high-energy flow batteries.
Enhanced iodine redox chemistry and iodine species anchoring play a determining role in the advancement of zinc-iodine (Zn-I2) batteries, and it remains a major challenge to
Collectively, these approaches not only improve electrochemical performance but also significantly extend battery cycle life, making them essential for the development of high
A zinc-iodine flow battery (ZIFB) with long cycle life, high energy, high power density, and self-healing behavior is prepared. The long cycle life was achieved by employing
With a focus on practical application, this work identifies key challenges in the field and proposes comprehensive optimization strategies, aiming to provide guidance for the
A zinc–iodine flow battery (ZIFB) with long cycle life, high energy, high power density, and self-healing behavior is prepared. The
A zinc–iodine flow battery (ZIFB) with long cycle life, high energy, high power density, and self-healing behavior is prepared. The long cycle life was achieved by employing
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Their high-energy density and iodide anion-rich electrolytes meet the demands of modern industries, enabling the initial large-scale application of zinc–iodine batteries for energy storage. However, storing electroactive substances in the electrolyte limits the utilization rate of iodine and reduces the battery's energy density.
Learn more. The growing demand for grid-scale energy storage calls for safe and low-cost solutions, for which zinc-iodine flow batteries (ZIFBs) are highly promising. However, their practical application is critically hindered by two issues: accumulation of insoluble solid iodine at the cathode and zinc dendrite growth at the anode.
In practical applications, the conventional method for loading active materials in batteries is mixing and coating. However, due to the low sublimation temperature of iodine, the active material in zinc–iodine batteries can benefit from a substrate designed during the loading process, enabling mass production of zinc–iodine batteries.
Aqueous zinc-iodine flow batteries show potential in large-scale storage but face water imbalance-induced instability. Here, authors develop a tailored ionic-molecular sieve membrane that selectively intercepts hydrated ions, enabling stable high-capacity long cycling with low projected costs.